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ISSN 2063-5346
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SYNTHESIS AND CRYSTALLOGRAPHIC CHARACTERIZA- TION OF MANGANESE(III) SCHIFF BASE COMPLEXES WITH AXIAL CARBOXYLATE LIGATION

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H. Roseben, K. L. Sreebala and V. S. Thampidas

Abstract

Two new complexes of manganese(III), [Mn(salen)(p-ClC6H4CO2)H2O] and [Mn(msalen)(C6H5CO2)H2O] have been synthesized from their manganese(II) carboxylate precursors [H2salen=N,N bis(salicylidene)-1,2-diaminoethane and H2msalen=N,N bis(3- methoxysalicylidene)-1,2-diaminoethane].

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