We obtained carbon composite materials with desired mechanical characteristics, electrical conductivity, magnetic properties, which are widely used in the production of rubbers, cables, sorption materials from various secondary raw materials like wastes of agricultural production (sawdust, fruit bones, coal industry wastes, etc.) with using a new thermochemical method. The composition of the obtained materials was carried out with scanning electron microscopy (SEM); Surface and porosity of the obtained materials were measured by use of instrument Gemini VII. Electrochemical Cu–C coatings were obtained with the use of carbon nanomaterials and tribological properties of the obtained coatings were investigated. The nanocarbon particles with large specific surface area and high porosity could also be used in composition electrocoating (CEC). The optimal concentration of carbon nanomaterials when CECs have best tribological properties has been determined.