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ISSN 2063-5346
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LONG TERM STUDY OF FULLERENE C60+• RADICAL CATION BY ELECTRON SPIN RESONANCE (ESR)

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Franco Cataldo and Susana Iglesias-Groth

Abstract

he dissolution of fullerene C60 in oleum (fuming sulphuric acid 20 % free SO3) was followed simultaneously with ESR (Electron Spin Resonance) and NIR (Near Infrared Spectroscopy). It is shown that the intensity of the ESR signal associated to the formation of C60 radical cation (C60+•) follows the same kinetics as the NIR absoption band at about 938 nm.

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