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ISSN 2063-5346
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COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLO-PROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE

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K. G. Guliyev,[a] A. M. Aliyeva,[a] S. B. Mamedli,[a] D. R. Nurullayeva,*, [a] A. M. Guliyev
» doi: 10.17628/ECB.2016.5.108

Abstract

The radical copolymerization of 2-(4-vinylphenyl)cyclopropylmethyl cinnamate with glycidyl methacrylate has been studied and new cyclopropane- and epoxy-group containing photosensitive copolymers have been prepared. The relative activity of monomers and the parameters of Q and e by Alfrey and Price method have been determined. The copolymerization constants of 2-(4-vinylphenyl)cyclopropylmethyl cinnamate (r1) and glycidyl methacrylate (r2) were determined by the Fineman-Ross method and proved to be r1 = 1.05 and r2 = 0.4, respectively; the parameters Q1 and e1 were found to be 1.82, -0.79, respectively. The composition and structure of this copolymer have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been established that during the photochemical transformation a re-structuring takes place due to cyclopropane and epoxide ring opening and reaction of double bond in cinnamate fragment as well.

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