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ISSN 2063-5346
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1,2-HYDROGEN MIGRATION IN AMINOALKYL RADICALS IN AMINATION REACTIONS OF α-OLEPHINS

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T. A. Aslanov,[a] E. T. Aslanova,[a]* N. R. Bektashi,[a] A. H. Azizov[a] and D. R. Nurullayeva
» doi: 10.17628/ECB.2016.5.495

Abstract

The amination of α-olefins (C4-C7) in the NН2OH·HCl-TiCl3 oxidation-reduction system was investigated and a number of mono- and diamines were prepared. It has been found that in the attack of NH2-radical to olefin a hydrogen migration from first carbon to second one takes place. It has been shown that in the reaction products, besides the desired individual amines, telomers, the molecular masses of which are approximately within the ranges of Мn = 460-800, were also detected

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