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ISSN 2063-5346
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INFRARED (FTIR) SPECTROSCOPY STUDY OF METAL IONS CU+2, FE+3, MN+2, CO+2 AND ZN+2 METAL IONS OF NOVEL POLYMERIC METAL CHELATES OF PATHQ

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Sanjay Kumar Saraf1, Arun Singh2*, Saroj Yadav3
» doi: 10.31838/ecb/2023.12.si5.048

Abstract

The novel polymeric ligands were prepared by reaction of 5-amino-8-quinolinol with polyamines containing cyanuric chloride moieties. These were characterized by preliminary characterization. Aim of recent study was to determined function group of polymeric metal chelates of PATHQ with Cu+2, Fe+3, Mn+2, Co+2 and Zn+2 metal ions by using FTIR spectroscopy method. All FTIR analysis was done in FTIR high efficiency instrument. The study results found variation of function group in ligand sample at wave length peak 3355 to 843 cm-1.Highest peak of FTIR results are found in 3066.42 (C-H of PL-1 and Cu2+), 3348.51 (O-H, PL-2 and Fe3+), 3194.03 (C-H,PL-3 and Zn2+), 3160.45 (N-H, PL-4 and Mn2+), 3355.22 (O-H, PL-5 and Co2+) and 3361.94 (O-H,PL-6 and Mn2+ ). Metal-oxygen new band is seen in the IR spectra.

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