Synthesis and Characterization of octakis[2-propyloxy-2-oxo-1-ethyl)thio]-21H, 23H-porphyrazine from 1,2-dicyano-1,2-thioethylene

Asieh Yahyazadeh, F. Sedigh Zyabari

Abstract


The 1, 2-dicyano-1, 2-bis (2-ethoxy-2-oxo-1-ethyl) thio ethylene has been prepared  from

sodium cis 1,2-dicyano 1,2-ethylenedithiolate (NAMNT) and ethyl chloroacetate by treatment with Sodium iodide in dry acetone.  2,3,7,8,12,13,17,18-Octakis[2-propyloxy-2-oxo-1-ethyl)thio]-21H,23H-porphyrazine was obtained  from 1,2-dicyano 1,2-bis (2-ethoxy-2-oxo-1-ethyl) thio ethylene in  proMg and dry  propanol.  All compounds have been fully characterized by spectroscopic data.

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DOI: http://dx.doi.org/10.17628/ecb.2013.2.584-585

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