2-Hydroxy-1-aryl-2-(indol-3’-yl)ethan-1-ones: Synthesis, Spectral Characteristics, Structure and their Rearrangement into 2-Hydroxy-2-aryl-1-(indol-3’-yl)ethan-1-ones

Vasiliy Georgievich Shtamburg, Victor Vasilievich Shtamburg, Andrey Alexandrovich Anishchenko, Alexander Vladimirovich Mazepa, Svetlana Vladimirovna Kravchenko, Svetlana Valentinovna Shishkina.

Abstract


The convenient methodic of synthesis of 2-hydroxy-1-aryl-2-(indol-3-yl)ethan-1-ones and their isomerization in 2-hydroxy-2-aryl-1-(indol-3-yl)ethan-1-ones in presence of triethylamine at heating or in presence of EtONa at room temperature were reported. The spectral tests of isomers structures are presented. By XRD study the structures of 2-hydroxy-1-phenyl-2-(indol-3-yl)ethan-1-one and 2-hydroxy-2-phenyl-1-(indol-3-yl)ethan-1-one have been researched.

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DOI: http://dx.doi.org/10.17628/ecb.0.0.223-232

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