1,2-HYDROGEN MIGRATION IN AMINOALKYL RADICALS

Elnara Telman Aslanova, Telman Agakerim Aslanov, Nazim Rauf Bektashi, Akif Hamid Azizov, Dilbar Rushan Nurullayeva

Abstract


The amination reaction of α-olefins C4-C7 in the oxidation-reduction system NН2OH∙HCl-TiCl3 has been investigated; as a result the mono- and diamines of various structures have been prepared. It has been found that in attack of -radical to olefin it takes place a hydrogen migration from first carbon to second one. It has been shown that in composition of the reaction products besides purposeful individual amines there are detected telomers, the molecular masses of which are changed approximately within the ranges of,  Мn = 460-800.

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DOI: http://dx.doi.org/10.17628/ecb.2016.5.495-500

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